H₂ SO₄ Alkylation
Olefins (C3-C4) from the FCC unit are combined with isobutane (i-C4). Concentrated Sulfuric Acid (H₂ SO₄) is then mixed in and fed to the reactor that is operated with refrigeration to minimize the formation of by-products. The alkylation reaction takes place, combining the olefins with the isobutane to form the alkylate product, which consists of high octane value products that are later blended into the gasoline pool. The hydrocarbons leaving the reactor mostly consist of alkylate, unreacted isobutane, n-butane, and propane.
The acid and alkylate products are separated by a settler, and the acid is recovered for re-use in the reactor. The reactor hydrocarbons are separated by the main fractionator where the isobutane is recycled to the reactor, alkylate is drawn from the bottom, and an n-butane product stream is separated from a side stream.
The light ends of the process fluids are used in the refrigeration loop and a side stream is passed through a propane stripper to recover propane. Effective separation is a critical component of an efficient, reliable, and safe sulfuric acid alkylation process.
- Equipment reliability/minimized corrosion to meet 4-6 year refinery turn around schedule
- Meet product specs for high octane value alkylate and caustic free propane
- Low acid makeup costs by minimizing acid dilution from wet feedstocks
- Maintain high levels of safety by avoiding any equipment failures that could lead to fugitive acid emissions
Production Challenge/Pall Solution
Meet product specifications.
Improve refinery productivity and product specifications by removal of water from the olefin and isobutane hydrocarbon reactor feed streams and by removing any carryover caustic in the propane.
Protect fractionator towers from corrosion & plugging.
Improve protection of main fractionator/isobutane stripper and propane stripper.
- High-efficiency PhaseSep liquid/liquid coalescers reliably remove caustic from the feed to the main fractionator / isobutane stripper and to the propane stripper tower to prevent corrosion and fouling of the internal trays.
Key Application/Filter Recommendations (other applications not shown)
Caustic removal from feed to propane stripper
Reduce corrosion in propane stripper and meet propane quality spec
Caustic removal from feed to main fractionator/isobutane stripper
Reduce corrosion in main fractionator and meet butane and alkylate purity specs
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